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投稿时间:2021-09-15 修订日期:2021-09-23
投稿时间:2021-09-15 修订日期:2021-09-23
中文摘要: 摘要:建立了微波消解-电感耦合等离子质谱(ICP-MS)同时测定淡水产品多11种金属元素的定量分析方法。比较了传统的湿法消解和微波消解两种消解方式对淡水产品测定影响。实验结果表明,微波消解方法不仅能够快速地将待测元素从淡水产品基体中释放出来,而且能够很好地保留在消解液中,待测元素的回收率较高。所建立方法测定了GBW10024(GSB-15)扇贝和GBW10051(GSB-29)猪肝标准物质,所得结果与标准值吻合度较高。采用微波消解-ICP-MS法测定市售的淡水产品中多种金属元素,其样品回收率在91.20%~110.81%。该方法快捷、准确、灵敏高,满足大批量淡水产品中金属元素分析测定要求,可为公安部门维护“食药环”领域安全稳定提供依据。
Abstract:Abstract:a quantitative method for simultaneous determination of 11 metal elements in freshwater products by microwave digestion inductively coupled plasma mass spectrometry (ICP-MS) was established. The effects of traditional wet digestion and microwave digestion on the determination of freshwater products were compared. The experimental results showed that the microwave digestion method can not only quickly release the elements to be measured from the matrix of fresh water products, but also retained them in the digestion solution, and the recovery rate of the elements to be measured is high. The established method was used to determine the reference materials of the GBW10024(GSB-15)of scallop and the GBW10051(GSB-29)of pork liver, and the results were in good agreement with the standard values. Microwave digestion ICP-MS method was used to determine various metal elements in commercial freshwater products. The sample recovery was 91.20% ~ 110.81%. The method is fast, accurate and sensitive, meets the requirements for the analysis and determination of metal elements in a large number of fresh water products, and can provide a basis for the public security department to maintain the safety and stability in the field of "food , drug and environment".
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学(42107308)和中国博士后基金(2019M652768)
Author Name | Affiliation | |
ZHAO Mingming | Hunan Police Academy | zmm_990103@126.com |
YI Rong-nan | Hunan Police Academy | yrn@hnu.edu.cn |
YANG Yuan | Hunan Agricultural University | yangyuan041@163.com |
引用文本:
赵明明,易荣楠,杨远.微波消解-电感耦合等离子体质谱法(ICP-MS)测定淡水产品中多种金属元素[J].中国无机分析化学,2021,11(6):41-45.
ZHAO Mingming,YI Rong-nan,YANG Yuan.Determination of multi-metallic elements in freshwater aquatic products by Inductively Coupled Plasma Mass Spectrometry(ICP-MS)with Microwave Digestion[J].Chinese Journal of Inorganic Analytical Chemistry,2021,11(6):41-45.
赵明明,易荣楠,杨远.微波消解-电感耦合等离子体质谱法(ICP-MS)测定淡水产品中多种金属元素[J].中国无机分析化学,2021,11(6):41-45.
ZHAO Mingming,YI Rong-nan,YANG Yuan.Determination of multi-metallic elements in freshwater aquatic products by Inductively Coupled Plasma Mass Spectrometry(ICP-MS)with Microwave Digestion[J].Chinese Journal of Inorganic Analytical Chemistry,2021,11(6):41-45.