Abstract:The soil samples were ground to pass 100-mesh sieve after air-dried, the water-soluble anions were extracted by deionized water, then filtered by 0.22μm membrane, the F_-^、BrO_3-^、Cl_-^、NO_2-^、Br_-^、NO_3-^、PO_43-^、SO_42- ^were separated by SUPP5 anion exchange column with 5.0 mmol/L Na₂CO₃ and 1.0 mmol/L NaHCO₃ solution as isocratic elution, then determined by ion chromatography with conductivity detector. The results showed that, the calibration curves of 8 kinds of anion had a good linearity in concentration range of 0.2~10.0 mg/L, the correlation coefficient was more than 0.999; The detection limits were 0.6~7.0 mg/kg_;Recovery test was made at 3 concentration levels, the recovery were 65.6%~120%, RSD were 0.2%~9.8%, which indicates that the method is high precision and accuracy; This method was used to detect the soil from vegetable planting base, farmland, green belt and pond silt, the results showed that F_-^, Cl_-^, NO_2-^, Br_-^, NO_3-^, PO_43- ^and SO_42- ^{were detected}, and the concentration were between 5.0 mg/kg~1090.6 mg/kg, while BrO_3- ^{was not detected}.