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投稿时间:2025-02-25 修订日期:2025-02-25
投稿时间:2025-02-25 修订日期:2025-02-25
中文摘要: 微塑料作为一种新型持久性污染物,已对生态系统构成潜在威胁,因此,有效进行微塑料的识别和分类工作对于环境污染的监测和风险评估至关重要,在现有的多种检测方法中,拉曼成像技术因其低样本需求及化学特异性强等优点被广泛应用于分析微塑料的类别和特征。为了应对MPs引发的生态环境问题,本研究探讨了高光谱解混方法与机器学习相结合的拉曼成像技术,用于识别和可视化土壤中的微塑料。其采用N-FINDR算法耦合无约束最小二乘法(N-FINDR-UCLS)分析聚苯乙烯(Polystyrene,PS)、聚丙烯(Polypropylene,PP)、聚乙烯(Polyethylene,PE)和聚己二酸/对苯二甲酸丁二醇酯(Poly(butylene adipate-co-terephthalate),PBAT)等四种常见的微塑料,分别对单一微塑料以及原始、老化和土壤中混合的微塑料进行了拉曼成像,并利用N-FINDR-UCLS分析,将其计算求得的平均光谱与原始微塑料拉曼数据进行对比,以皮尔逊相关系数(r)评价光谱图的相似性和鲁棒性。结果显示,该方法能够快速准确地识别单一以及原始和老化微塑料多元混合的微塑料类型,并在复杂的土壤样品中保持良好的识别能力。在微塑料污染日益严重的背景下,该方法为环境监测和污染治理提供了强有力的工具,未来的研究可以进一步优化算法,引入更多种类的微塑料样本,并探索在其他复杂环境中的应用。
Abstract:Microplastics (MPs) pollution has become an important issue in the global environmental field. In particular, their persistent accumulation in soil environments could pose significant threats to ecosystems and human health over time. Consequently, the development of effective detection and identification techniques for MPs is essential for environmental monitoring and remediation efforts. While advances have been made in the identification of MPs using Raman spectroscopy coupled with machine learning, a significant challenge remains: the requirement for extensive datasets, the collection of which can be both time-consuming and costly. Thus, this study aims to explore a Raman imaging technique that combines hyperspectral unmixing methods with machine learning for the identification and visualization of MPs in soil. The primary advantage of this approach lies in its ability to achieve high-precision identification of target samples without reliance on large datasets, making it both cost-effective and efficient.
keywords: microplastics hyperspectral unmixing Raman imaging machine learning environmental detection
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学(42371079);天山北坡土地开发利用过程中耕地土壤质量调查(2022xjkk0901)
MA Mengdan XU Yuzhi LI Fang XU Li
School of Resources and Environmental Engineering,Shandong University of Technology,Zibo,School of Resources and Environmental Engineering,Shandong University of Technology,Zibo,Beijing Academy of Agriculture and Forestry Sciences,Institute of Quality Standard and Testing Technology,Beijing Academy of Agriculture and Forestry Sciences,Institute of Quality Standard and Testing Technology
School of Resources and Environmental Engineering,Shandong University of Technology,Zibo,School of Resources and Environmental Engineering,Shandong University of Technology,Zibo,Beijing Academy of Agriculture and Forestry Sciences,Institute of Quality Standard and Testing Technology,Beijing Academy of Agriculture and Forestry Sciences,Institute of Quality Standard and Testing Technology
引用文本:
马梦丹,许玉芝,李芳,徐笠.基于机器学习的拉曼成像技术在微塑料识别与可视化中的应用[J].中国无机分析化学,2025,15(7):939-949.
MA Mengdan,XU Yuzhi,LI Fang,XU Li.Application of Machine Learning-Based Raman Imaging Technology in the Identification and Visualization of Microplastics[J].Chinese Journal of Inorganic Analytical Chemistry,2025,15(7):939-949.
马梦丹,许玉芝,李芳,徐笠.基于机器学习的拉曼成像技术在微塑料识别与可视化中的应用[J].中国无机分析化学,2025,15(7):939-949.
MA Mengdan,XU Yuzhi,LI Fang,XU Li.Application of Machine Learning-Based Raman Imaging Technology in the Identification and Visualization of Microplastics[J].Chinese Journal of Inorganic Analytical Chemistry,2025,15(7):939-949.

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