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Rapid Determination of Copper in Matte by Iodimetry Combined with Ammonia-Ammonium Chloride Secondary Precipitation |
Received:May 17, 2015 Revised:July 16, 2015 |
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DOI:doi:10.3969/j.issn.2095-1035.2015.04.015 |
KeyWord:matte; nitrate–potassium; chlorate secondary precipitation; iodimetry |
Author | Institution |
HU Yanqiao |
河北省地矿中心实验室,河北 保定 |
CHENG Wencui |
河北省地矿中心实验室,河北 保定 |
ZHI Yunchuan |
河北省地矿中心实验室,河北 保定 |
WEI Li |
河北省地矿中心实验室,河北 保定 |
ZHANG Jinming |
河北省地矿中心实验室,河北 保定 |
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Abstract: |
According to the characteristics of matrix composition of matte, a pre-treatment method of copper in matte was improved on the base of traditional iodimetry. The sample was dissolved by nitrate–potassium chlorate for removing sulfur, and then copper was obtained by ammonia-ammonium chloride secondary precipitation. Thus, the content of copper could be directly determined. The proposed method can not only meet the requirement for rapid determination copper in matte by iodimetry, but also reduce the procedure of atomic absorption and supplement. The results indicated that the relative standard deviation (RSD) was 0.61%~1.9%. The method has been verified by national certified reference materials and compared with other methods, and the accuracy and precision were satisfactory. It is characterized by convenience, rapid analytical speed and efficiency to apply. |
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